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Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W(v)–Co(ii) cyanide single-chain magnet
A new octacyanotungstate(v) based single chain magnet {[(Tpm)Co(DMF)W(CN)(8)](2)[Co(DMF)(4)]·2DMF}(n) (1, Tpm = 1,1,1-trispyrazoylmethane), with an effective barrier of 39.7(3) cm(–1) is reported. The Ising-like magnetic anisotropy of the chain originates from the nearly parallel local orientations...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5873217/ https://www.ncbi.nlm.nih.gov/pubmed/29629079 http://dx.doi.org/10.1039/c7sc02925j |