Cobalt-catalyzed regioselective stereoconvergent Markovnikov 1,2-hydrosilylation of conjugated dienes

We report the first stereoconvergent Markovnikov 1,2-hydrosilylation of conjugated dienes using catalysts generated from bench-stable Co(acac)(2) and phosphine ligands. A wide range of E/Z-dienes underwent this Markovnikov 1,2-hydrosilylation in a stereoconvergent manner, affording (E)-allylsilanes...

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Detalles Bibliográficos
Autores principales: Sang, Hui Leng, Yu, Songjie, Ge, Shaozhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5873224/
https://www.ncbi.nlm.nih.gov/pubmed/29629163
http://dx.doi.org/10.1039/c7sc04002d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5873224/
https://www.ncbi.nlm.nih.gov/pubmed/29629163
http://dx.doi.org/10.1039/c7sc04002d

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