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Models for aerobic carbon monoxide dehydrogenase: synthesis, characterization and reactivity of paramagnetic Mo(V)O(μ-S)Cu(I) complexes
Reaction of [CoCp(2)][Tp(iPr)MoOS(OAr)] [Cp = η(5)-cyclopentadienyl; Tp(iPr) = hydrotris(3-isopropylpyrazol-1-yl)borate; OAr = phenolate or derivative thereof] with [Cu(NCMe)(Me(3)tcn)]BF(4) (Me(3)tcn = 1,4,7-trimethyl-1,4,7-triazacyclononane) in MeCN at –30 °C results in the formation of red-brown/...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5873225/ https://www.ncbi.nlm.nih.gov/pubmed/29629154 http://dx.doi.org/10.1039/c7sc04239f |