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Models for aerobic carbon monoxide dehydrogenase: synthesis, characterization and reactivity of paramagnetic Mo(V)O(μ-S)Cu(I) complexes

Reaction of [CoCp(2)][Tp(iPr)MoOS(OAr)] [Cp = η(5)-cyclopentadienyl; Tp(iPr) = hydrotris(3-isopropylpyrazol-1-yl)borate; OAr = phenolate or derivative thereof] with [Cu(NCMe)(Me(3)tcn)]BF(4) (Me(3)tcn = 1,4,7-trimethyl-1,4,7-triazacyclononane) in MeCN at –30 °C results in the formation of red-brown/...

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Detalles Bibliográficos
Autores principales:	Gourlay, Craig, Nielsen, David J., Evans, David J., White, Jonathan M., Young, Charles G.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5873225/ https://www.ncbi.nlm.nih.gov/pubmed/29629154 http://dx.doi.org/10.1039/c7sc04239f

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