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Organocatalytic nitrenoid transfer: metal-free selective intermolecular C(sp(3))–H amination catalyzed by an iminium salt
This report details the first organocatalytic method for nitrenoid transfer and its application to intermolecular, site-selective C(sp(3))–H amination. The method utilizes a trifluoromethyl iminium salt as the catalyst, iminoiodinanes as the nitrogen source, and substrate as the limiting reagent. Ac...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5874695/ https://www.ncbi.nlm.nih.gov/pubmed/29629160 http://dx.doi.org/10.1039/c7sc03968a |