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Are multiple oxygen species selective in ethylene epoxidation on silver?

The nature of the oxygen species active in ethylene epoxidation is a long-standing question. While the structure of the oxygen species that participates in total oxidation (nucleophilic oxygen) is known the atomic structure of the selective species (electrophilic oxygen) is still debated. Here, we u...

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Detalles Bibliográficos
Autores principales: Carbonio, Emilia A., Rocha, Tulio C. R., Klyushin, Alexander Yu., Píš, Igor, Magnano, Elena, Nappini, Silvia, Piccinin, Simone, Knop-Gericke, Axel, Schlögl, Robert, Jones, Travis E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5874983/
https://www.ncbi.nlm.nih.gov/pubmed/29629166
http://dx.doi.org/10.1039/c7sc04728b