Stereoselective construction of sterically hindered oxaspirocycles via chiral bidentate directing group-mediated C(sp(3))–O bond formation

The systematic investigation of chiral bidentate auxiliaries has resulted in the discovery of a chiral 2,2-dimethyl-1-(pyridin-2-yl)propan-1-amine-derived directing group that enables stereoselective palladium(ii)-catalyzed intramolecular C(sp(3))–O bond formation. This new chiral directing group ex...

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Detalles Bibliográficos
Autores principales: Kim, Yechan, Kim, Seoung-Tae, Kang, Dahye, Sohn, Te-ik, Jang, Eunyoung, Baik, Mu-Hyun, Hong, Sungwoo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5875089/
https://www.ncbi.nlm.nih.gov/pubmed/29629170
http://dx.doi.org/10.1039/c7sc04691j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5875089/
https://www.ncbi.nlm.nih.gov/pubmed/29629170
http://dx.doi.org/10.1039/c7sc04691j

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