Cargando…
Stereoselective construction of sterically hindered oxaspirocycles via chiral bidentate directing group-mediated C(sp(3))–O bond formation
The systematic investigation of chiral bidentate auxiliaries has resulted in the discovery of a chiral 2,2-dimethyl-1-(pyridin-2-yl)propan-1-amine-derived directing group that enables stereoselective palladium(ii)-catalyzed intramolecular C(sp(3))–O bond formation. This new chiral directing group ex...
| Autores principales: | , , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5875089/ https://www.ncbi.nlm.nih.gov/pubmed/29629170 http://dx.doi.org/10.1039/c7sc04691j |