Cyclopropanations via Heme Carbenes: Basic Mechanism and Effects of Carbene Substituent, Protein Axial Ligand, and Porphyrin Substitution

[Image: see text] Catalytic carbene transfer to olefins is a useful approach to synthesize cyclopropanes, which are key structural motifs in many drugs and biologically active natural products. While catalytic methods for olefin cyclopropanation have largely relied on rare transition-metal-based cat...

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Detalles Bibliográficos
Autores principales: Wei, Yang, Tinoco, Antonio, Steck, Viktoria, Fasan, Rudi, Zhang, Yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5875692/
https://www.ncbi.nlm.nih.gov/pubmed/29268614
http://dx.doi.org/10.1021/jacs.7b09171

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5875692/
https://www.ncbi.nlm.nih.gov/pubmed/29268614
http://dx.doi.org/10.1021/jacs.7b09171

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