Cargando…
The mechanism of directed Ni(ii)-catalyzed C–H iodination with molecular iodine
The density functional theory method is used to elucidate the elementary steps of Ni(ii)-catalyzed C(sp(2))–H iodination with I(2) and substrates bearing N,N′-bidentate directing centers, amide-oxazoline (AO) and 8-aminoquinoline (AQ). The relative stability of the lowest energy high- and low-spin e...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5883947/ https://www.ncbi.nlm.nih.gov/pubmed/29675159 http://dx.doi.org/10.1039/c7sc04604a |