Site-selective (18)F fluorination of unactivated C–H bonds mediated by a manganese porphyrin

The first direct C–H (18)F fluorination reaction of unactivated aliphatic sites using no-carrier-added [(18)F]fluoride is reported. Under the influence of a manganese porphyrin/iodosylbenzene system, a variety of unactivated aliphatic C–H bonds can be selectively converted to C–(18)F bonds. The mild...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Wei, Huang, Xiongyi, Placzek, Michael S., Krska, Shane W., McQuade, Paul, Hooker, Jacob M., Groves, John T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5885592/
https://www.ncbi.nlm.nih.gov/pubmed/29675161
http://dx.doi.org/10.1039/c7sc04545j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5885592/
https://www.ncbi.nlm.nih.gov/pubmed/29675161
http://dx.doi.org/10.1039/c7sc04545j

Ejemplares similares