Alkylative kinetic resolution of vicinal diols under phase-transfer conditions: a chiral ammonium borinate catalysis

Herein, we report the first alkylative kinetic resolution of vicinal alcohols realized by cooperative use of a chiral quaternary ammonium salt and an achiral borinic acid. In addition, a catalytic regioselective alkylation of a secondary alcohol in the presence of an unprotected primary one is prese...

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Detalles Bibliográficos
Autores principales: Pawliczek, Martin, Hashimoto, Takuya, Maruoka, Keiji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5885781/
https://www.ncbi.nlm.nih.gov/pubmed/29675168
http://dx.doi.org/10.1039/c7sc04854h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5885781/
https://www.ncbi.nlm.nih.gov/pubmed/29675168
http://dx.doi.org/10.1039/c7sc04854h

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