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Reactivity of highly Lewis acidic diborane(4) towards pyridine and isocyanide: formation of boraalkene–pyridine complex and ortho-functionalized pyridine derivatives

The reaction of pinB-BMes(2) (pin = pinacolato, Mes = 2,4,6-Me(3)C(6)H(2)) with Xyl-NC (Xyl = 2,6-Me(2)C(6)H(3)) and pyridine results in the formation of a pyridine-coordinated boraalkene that exhibits an intense color caused by an intramolecular charge-transfer interaction. In the presence of an ex...

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Detalles Bibliográficos
Autores principales: Katsuma, Yuhei, Asakawa, Hiroki, Yamashita, Makoto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5887101/
https://www.ncbi.nlm.nih.gov/pubmed/29675176
http://dx.doi.org/10.1039/c7sc04759b