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Pore closure in zeolitic imidazolate frameworks under mechanical pressure

We investigate the pressure-dependent mechanical behaviour of the zeolitic imidazolate framework ZIF-4 (M(im)(2); M(2+) = Co(2+) or Zn(2+), im(–) = imidazolate) with high pressure, synchrotron powder X-ray diffraction and mercury intrusion measurements. A displacive phase transition from a highly co...

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Detalles Bibliográficos
Autores principales: Henke, Sebastian, Wharmby, Michael T., Kieslich, Gregor, Hante, Inke, Schneemann, Andreas, Wu, Yue, Daisenberger, Dominik, Cheetham, Anthony K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5887855/
https://www.ncbi.nlm.nih.gov/pubmed/29675212
http://dx.doi.org/10.1039/c7sc04952h