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Pore closure in zeolitic imidazolate frameworks under mechanical pressure
We investigate the pressure-dependent mechanical behaviour of the zeolitic imidazolate framework ZIF-4 (M(im)(2); M(2+) = Co(2+) or Zn(2+), im(–) = imidazolate) with high pressure, synchrotron powder X-ray diffraction and mercury intrusion measurements. A displacive phase transition from a highly co...
Autores principales: | Henke, Sebastian, Wharmby, Michael T., Kieslich, Gregor, Hante, Inke, Schneemann, Andreas, Wu, Yue, Daisenberger, Dominik, Cheetham, Anthony K. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5887855/ https://www.ncbi.nlm.nih.gov/pubmed/29675212 http://dx.doi.org/10.1039/c7sc04952h |
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