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Cobaltocenylidene: A Mesoionic Metalloceno Carbene, Stabilized in a Gold(III) Complex

Oxidative addition of cobaltoceniumdiazonium bis(hexafluoridophosphate) with (pseudo)halide aurates gave gold(III) complexes containing zwitterionic cobaltoceniumide as a ligand. Its selenium derivative, cobaltoceniumselenolate, was obtained by an electrophilic aromatic substitution reaction of iodo...

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Detalles Bibliográficos
Autores principales: Vanicek, Stefan, Podewitz, Maren, Hassenrück, Christopher, Pittracher, Michael, Kopacka, Holger, Wurst, Klaus, Müller, Thomas, Liedl, Klaus R., Winter, Rainer F., Bildstein, Benno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5888181/
https://www.ncbi.nlm.nih.gov/pubmed/29328533
http://dx.doi.org/10.1002/chem.201800147