Cargando…

Cobaltocenylidene: A Mesoionic Metalloceno Carbene, Stabilized in a Gold(III) Complex

Oxidative addition of cobaltoceniumdiazonium bis(hexafluoridophosphate) with (pseudo)halide aurates gave gold(III) complexes containing zwitterionic cobaltoceniumide as a ligand. Its selenium derivative, cobaltoceniumselenolate, was obtained by an electrophilic aromatic substitution reaction of iodo...

Descripción completa

Detalles Bibliográficos
Autores principales:	Vanicek, Stefan, Podewitz, Maren, Hassenrück, Christopher, Pittracher, Michael, Kopacka, Holger, Wurst, Klaus, Müller, Thomas, Liedl, Klaus R., Winter, Rainer F., Bildstein, Benno
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2018
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5888181/ https://www.ncbi.nlm.nih.gov/pubmed/29328533 http://dx.doi.org/10.1002/chem.201800147

Ejemplares similares

Curious Case of Cobaltocenium Carbaldehyde
por: Menia, Daniel, et al.
Publicado: (2023)

Mesoionic Carbenes in Low- to High-Valent Vanadium Chemistry
por: Neururer, Florian R., et al.
Publicado: (2021)

Redox-Rich Metallocene Tetrazene Complexes: Synthesis, Structure, Electrochemistry, and Catalysis
por: Vanicek, Stefan, et al.
Publicado: (2018)

N-Heterocyclic Carbene Gold(I) Complexes: Mechanism of the Ligand Scrambling Reaction and Their Oxidation to Gold(III) in Aqueous Solutions
por: Goetzfried, Sina K., et al.
Publicado: (2020)

Highly Electrophilic, Catalytically Active and Redox‐Responsive Cobaltoceniumyl and Ferrocenyl Triazolylidene Coinage Metal Complexes
por: Vanicek, Stefan, et al.
Publicado: (2018)

Cationic Cycloheptatrienyl Cyclopentadienyl Manganese Sandwich Complexes: Tromancenium Explored with High-Power LED Photosynthesis
por: Basse, Reinhard, et al.
Publicado: (2021)

Rhodocenium Functionalization Enabled by Half‐Sandwich Capping, Zincke Reaction, Diazoniation and Sandmeyer Chemistry
por: Wiedemair, Markus, et al.
Publicado: (2021)

Cobaltoceniumselenolate Gold(I) Complexes: Synthesis, Spectroscopic, Structural and Anticancer Properties
por: Menia, Daniel, et al.
Publicado: (2021)

Crystal structures of 1′-aminocobaltocenium-1-carboxylic acid chloride monohydrate and of its azo dye 1′-[2-(1-amino-2,6-dimethylphenyl)diazen-1-yl]cobaltocenium-1-carboxylic acid hexafluoridophosphate monohydrate
por: Jochriem, Markus, et al.
Publicado: (2019)

Borylated Cymantrenes and Tromancenium Salts with Unusual Reactivity
por: Thaler, Reinhard, et al.
Publicado: (2022)

Stabilization of Boron–Boron Triple Bonds by Mesoionic Carbenes
por: Saha, Ranajit, et al.
Publicado: (2018)

Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV)
por: Seed, John A., et al.
Publicado: (2022)

Mechanism of Olefin Metathesis with Neutral and Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes
por: Herz, Katharina, et al.
Publicado: (2019)

Pyro‐Phyllobilins: Elusive Chlorophyll Catabolites Lacking a Critical Carboxylate Function of the Natural Chlorophylls
por: Li, Chengjie, et al.
Publicado: (2018)

Copper(I) Complexes of Mesoionic Carbene: Structural Characterization and Catalytic Hydrosilylation Reactions
por: Hohloch, Stephan, et al.
Publicado: (2015)

Chemistry of Compounds Based on 1,2,3-Triazolylidene-Type Mesoionic Carbenes
por: Maity, Ramananda, et al.
Publicado: (2021)

The Core Difference between a Mesoionic and a Normal N-Heterocyclic Carbene
por: Barnett, Christopher, et al.
Publicado: (2022)

Chlorophyll‐Derived Yellow Phyllobilins of Higher Plants as Medium‐Responsive Chiral Photoswitches
por: Li, Chengjie, et al.
Publicado: (2016)

Nickel‐Catalyzed Intramolecular 1,2‐Aryl Migration of Mesoionic Carbenes (iMICs)
por: Merschel, Arne, et al.
Publicado: (2020)

Tuning the π‐Accepting Properties of Mesoionic Carbenes: A Combined Computational and Experimental Study
por: Dong, Zhaowen, et al.
Publicado: (2021)

Bis(μ-cobaltoceniumselenolate-1:2κ(2) Se:Se)bis[bis(cobaltoceniumselenolate-κSe)mercury(II)] tetrakis(hexafluoridophosphate) acetonitrile disolvate
por: Menia, Daniel, et al.
Publicado: (2021)

(η(5)-Carboxycyclopentadienyl)(η(7)-cycloheptatrienyl)manganese(I) hexafluoridophosphate
por: Thaler, Reinhard, et al.
Publicado: (2023)

Palladium Mesoionic Carbene Pre-catalyst for General Cross-Coupling Transformations in Deep Eutectic Solvents
por: Marset, Xavier, et al.
Publicado: (2019)

Sydnone Methides—A Forgotten Class of Mesoionic Compounds for the Generation of Anionic N‐Heterocyclic Carbenes
por: Mummel, Sebastian, et al.
Publicado: (2021)

Rare‐Earth‐ and Uranium‐Mesoionic Carbenes: A New Class of f‐Block Carbene Complex Derived from an N‐Heterocyclic Olefin
por: Seed, John A., et al.
Publicado: (2017)

Direct Amination of Cobaltocenium Hexafluoridophosphate via Vicarious Nucleophilic Substitution
por: Jochriem, Markus, et al.
Publicado: (2019)

Phosphorescent Tris-cyclometalated Pt(IV) Complexes with Mesoionic N-Heterocyclic Carbene and 2-Arylpyridine Ligands
por: Vivancos, Ángela, et al.
Publicado: (2022)

(Cobaltoceniumylamido)pyridinium hexafluoridophosphate
por: Menia, Daniel, et al.
Publicado: (2021)

Palladium(ii)-Acetylacetonato Complexes with Mesoionic Carbenes: Synthesis, Structures and Their Application in the Suzuki-Miyaura Cross Coupling Reaction
por: Hettmanczyk, Lara, et al.
Publicado: (2016)

Strongly Luminescent Pt(IV) Complexes with a Mesoionic N-Heterocyclic Carbene Ligand: Tuning Their Photophysical Properties
por: Vivancos, Ángela, et al.
Publicado: (2021)

Cu[B(2)(SO(4))(4)] and Cu[B(SO(4))(2)(HSO(4))]—Two Silicate Analogue Borosulfates Differing in their Dimensionality: A Comparative Study of Stability and Acidity
por: Bruns, Jörn, et al.
Publicado: (2018)

Replacement of the Cobalt Center of Vitamin B(12) by Nickel: Nibalamin and Nibyric Acid Prepared from Metal‐Free B(12) Ligands Hydrogenobalamin and Hydrogenobyric Acid
por: Kieninger, Christoph, et al.
Publicado: (2020)

Enthalpic and Entropic Contributions to Hydrophobicity
por: Schauperl, Michael, et al.
Publicado: (2016)

Impact of Bidentate Pyridyl-Mesoionic Carbene Ligands: Structural, (Spectro)Electrochemical, Photophysical, and Theoretical Investigations on Ruthenium(II) Complexes
por: Bens, Tobias, et al.
Publicado: (2023)

On the Origin of E-Selectivity in the Ring-Opening Metathesis Polymerization with Molybdenum Imido Alkylidene N-Heterocyclic Carbene Complexes
por: Podewitz, Maren, et al.
Publicado: (2021)

Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides
por: Rottschäfer, Dennis, et al.
Publicado: (2019)

Isomerization Reactions in Anionic Mesoionic Carbene‐Borates and Control of Properties and Reactivities in the Resulting Co(II) Complexes through Agostic Interactions
por: Stubbe, Jessica, et al.
Publicado: (2020)

The transformations of a methylene-bridged bis-triazolium salt: a mesoionic carbene based metallocage and analogues of TCNE and NacNac
por: Stubbe, Jessica, et al.
Publicado: (2021)

On the synergy of matrix-isolation infrared spectroscopy and vibrational configuration interaction computations
por: Dinu, Dennis F., et al.
Publicado: (2020)

Toward Elimination of Discrepancies between Theory and Experiment: Anharmonic Rotational–Vibrational Spectrum of Water in Solid Noble Gas Matrices
por: Dinu, Dennis F., et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_o2kt8h6vs1svfroahkiilj6cal