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Diazomethane umpolung atop anthracene: an electrophilic methylene transfer reagent
Formal addition of diazomethane's terminal nitrogen atom to the 9,10-positions of anthracene yields H(2)CN(2)A (1, A = C(14)H(10) or anthracene). The synthesis of this hydrazone is reported from Carpino's hydrazine H(2)N(2)A through treatment with paraformaldehyde. Compound 1 has been foun...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5890322/ https://www.ncbi.nlm.nih.gov/pubmed/29675198 http://dx.doi.org/10.1039/c7sc04506a |