Metal alkyls programmed to generate metal alkylidenes by α-H abstraction: prognosis from NMR chemical shift

Metal alkylidenes, which are key organometallic intermediates in reactions such as olefination or alkene and alkane metathesis, are typically generated from metal dialkyl compounds [M](CH(2)R)(2) that show distinctively deshielded chemical shifts for their α-carbons. Experimental solid-state NMR mea...

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Detalles Bibliográficos
Autores principales: Gordon, Christopher P., Yamamoto, Keishi, Searles, Keith, Shirase, Satoru, Andersen, Richard A., Eisenstein, Odile, Copéret, Christophe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5890791/
https://www.ncbi.nlm.nih.gov/pubmed/29675237
http://dx.doi.org/10.1039/c7sc05039a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5890791/
https://www.ncbi.nlm.nih.gov/pubmed/29675237
http://dx.doi.org/10.1039/c7sc05039a

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