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Metal alkyls programmed to generate metal alkylidenes by α-H abstraction: prognosis from NMR chemical shift

Metal alkylidenes, which are key organometallic intermediates in reactions such as olefination or alkene and alkane metathesis, are typically generated from metal dialkyl compounds [M](CH(2)R)(2) that show distinctively deshielded chemical shifts for their α-carbons. Experimental solid-state NMR mea...

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Detalles Bibliográficos
Autores principales:	Gordon, Christopher P., Yamamoto, Keishi, Searles, Keith, Shirase, Satoru, Andersen, Richard A., Eisenstein, Odile, Copéret, Christophe
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5890791/ https://www.ncbi.nlm.nih.gov/pubmed/29675237 http://dx.doi.org/10.1039/c7sc05039a

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