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NHC and nucleophile chelation effects on reactive iron(ii) species in alkyl–alkyl cross-coupling

While iron–NHC catalysed cross-couplings have been shown to be effective for a wide variety of reactions (e.g. aryl–aryl, aryl–alkyl, alkyl–alkyl), the nature of the in situ formed and reactive iron species in effective catalytic systems remains largely undefined. In the current study, freeze-trappe...

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Detalles Bibliográficos
Autores principales: Fleischauer, Valerie E., Muñoz III, Salvador B., Neate, Peter G. N., Brennessel, William W., Neidig, Michael L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5890793/
https://www.ncbi.nlm.nih.gov/pubmed/29675234
http://dx.doi.org/10.1039/c7sc04750a