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First use of a divalent lanthanide for visible-light-promoted photoredox catalysis

We report the first catalytic use of a divalent lanthanide in visible-light-promoted bond-forming reactions. Our new precatalyst uses europium in the +2 oxidation state and is active in the presence of blue light from light-emitting diodes. The use of low-energy visible light reduces the occurrence...

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Detalles Bibliográficos
Autores principales: Jenks, Tyler C., Bailey, Matthew D., Hovey, Jessica L., Fernando, Shanilke, Basnayake, Gihan, Cross, Michael E., Li, Wen, Allen, Matthew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5890796/
https://www.ncbi.nlm.nih.gov/pubmed/29675173
http://dx.doi.org/10.1039/c7sc02479g