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Mechanistic insights into boron-catalysed direct amidation reactions

The generally accepted monoacyloxyboron mechanism of boron-catalysed direct amidation is brought into question in this study, and new alternatives are proposed. We have carried out a detailed investigation of boron-catalysed amidation reactions, through study of the interaction between amines/carbox...

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Detalles Bibliográficos
Autores principales: Arkhipenko, Sergey, Sabatini, Marco T., Batsanov, Andrei S., Karaluka, Valerija, Sheppard, Tom D., Rzepa, Henry S., Whiting, Andrew
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5890798/
https://www.ncbi.nlm.nih.gov/pubmed/29675153
http://dx.doi.org/10.1039/c7sc03595k