[(Cp(2)M)(2)B(9)H(11)] (M = Zr or Hf): early transition metal ‘guarded’ heptaborane with strong covalent and electrostatic bonding

Among the series of stable closo-borate dianions, [B(n)H(n)](2–), the X-ray crystallographic structure of [B(7)H(7)](2–) was determined only in 2011. To explore its chemistry and stability, we have isolated and structurally characterized two new transition metal complexes of the heptaborane, [(Cp(2)...

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Detalles Bibliográficos
Autores principales: De, Anangsha, Zhang, Qian-Fan, Mondal, Bijan, Cheung, Ling Fung, Kar, Sourav, Saha, Koushik, Varghese, Babu, Wang, Lai-Sheng, Ghosh, Sundargopal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5892308/
https://www.ncbi.nlm.nih.gov/pubmed/29675244
http://dx.doi.org/10.1039/c7sc05014c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5892308/
https://www.ncbi.nlm.nih.gov/pubmed/29675244
http://dx.doi.org/10.1039/c7sc05014c

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