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Porphyrinoids as a platform of stable radicals

The non-innocent ligand nature of porphyrins was observed for compound I in enzymatic cycles of cytochrome P450. Such porphyrin radicals were first regarded as reactive intermediates in catabolism, but recent studies have revealed that porphyrinoids, including porphyrins, ring-contracted porphyrins,...

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Detalles Bibliográficos
Autores principales: Shimizu, Daiki, Osuka, Atsuhiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5892410/
https://www.ncbi.nlm.nih.gov/pubmed/29675188
http://dx.doi.org/10.1039/c7sc05210c