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Absolute and relative facial selectivities in organocatalytic asymmetric chlorocyclization reactions

Though (DHQD)(2)PHAL-catalyzed chlorocyclizations of 1,1-disubstituted olefins show useful (and in some cases, reversible) asymmetric induction, stereochemically complete descriptions of these alkene additions have remained largely unknown. Herein, based on a combination of NMR, derivative, isotope...

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Detalles Bibliográficos
Autores principales: Salehi Marzijarani, Nastaran, Yousefi, Roozbeh, Jaganathan, Arvind, Ashtekar, Kumar Dilip, Jackson, James E., Borhan, Babak
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5896375/
https://www.ncbi.nlm.nih.gov/pubmed/29719676
http://dx.doi.org/10.1039/c7sc04430e