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A combined experimental and computational study on the reaction of fluoroarenes with Mg–Mg, Mg–Zn, Mg–Al and Al–Zn bonds
Through a combined experimental and computational (DFT) approach, the reaction mechanism of the addition of fluoroarenes to Mg–Mg bonds has been determined as a concerted S(N)Ar-like pathway in which one Mg centre acts as a nucleophile and the other an electrophile. The experimentally determined Gib...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5897846/ https://www.ncbi.nlm.nih.gov/pubmed/29719707 http://dx.doi.org/10.1039/c7sc05059c |