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Determinant Role of Electrogenerated Reactive Nucleophilic Species on Selectivity during Reduction of CO(2) Catalyzed by Metalloporphyrins
[Image: see text] This work provides insights to understand the selectivity during the reduction of CO(2) with metalloporphyrin (MP) catalysts. The attack of a nucleophile on the carbon of the CO(2) appears as an important event that triggers the catalytic reaction, and the nature of this nucleophil...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5897864/ https://www.ncbi.nlm.nih.gov/pubmed/29551059 http://dx.doi.org/10.1021/jacs.7b11267 |