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Determinant Role of Electrogenerated Reactive Nucleophilic Species on Selectivity during Reduction of CO(2) Catalyzed by Metalloporphyrins

[Image: see text] This work provides insights to understand the selectivity during the reduction of CO(2) with metalloporphyrin (MP) catalysts. The attack of a nucleophile on the carbon of the CO(2) appears as an important event that triggers the catalytic reaction, and the nature of this nucleophil...

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Detalles Bibliográficos
Autores principales: Göttle, Adrien J., Koper, Marc T. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5897864/
https://www.ncbi.nlm.nih.gov/pubmed/29551059
http://dx.doi.org/10.1021/jacs.7b11267

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