Closely related yet different: a borylene and its dimer are non-interconvertible but connected through reactivity

The self-stabilizing, tetrameric cyanoborylene [(cAAC)B(CN)](4) (I, cAAC = 1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene) and its diborene relative, [(cAAC)(CN)B[double bond, length as m-dash]B(CN)(cAAC)] (II), both react with disulfides and diselenides to yield the corresponding...

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Detalles Bibliográficos
Autores principales: Auerhammer, Dominic, Arrowsmith, Merle, Dewhurst, Rian D., Kupfer, Thomas, Böhnke, Julian, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5897878/
https://www.ncbi.nlm.nih.gov/pubmed/29719698
http://dx.doi.org/10.1039/c7sc04789d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5897878/
https://www.ncbi.nlm.nih.gov/pubmed/29719698
http://dx.doi.org/10.1039/c7sc04789d

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