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Local protein solvation drives direct down-conversion in phycobiliprotein PC645 via incoherent vibronic transport

The mechanisms controlling excitation energy transport (EET) in light-harvesting complexes remain controversial. Following the observation of long-lived beats in 2D electronic spectroscopy of PC645, vibronic coherence, the delocalization of excited states between pigments supported by a resonant vib...

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Detalles Bibliográficos
Autores principales: Blau, Samuel M., Bennett, Doran I. G., Kreisbeck, Christoph, Scholes, Gregory D., Aspuru-Guzik, Alán
Formato: Online Artículo Texto
Lenguaje:English
Publicado: National Academy of Sciences 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5899487/
https://www.ncbi.nlm.nih.gov/pubmed/29588417
http://dx.doi.org/10.1073/pnas.1800370115