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Stepwise radical cation Diels–Alder reaction via multiple pathways

Herein we disclose the radical cation Diels–Alder reaction of aryl vinyl ethers by electrocatalysis, which is triggered by an oxidative SET process. The reaction clearly proceeds in a stepwise fashion, which is a rare mechanism in this class. We also found that two distinctive pathways, including “d...

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Detalles Bibliográficos
Autores principales: Shimizu, Ryo, Okada, Yohei, Chiba, Kazuhiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5905251/
https://www.ncbi.nlm.nih.gov/pubmed/29719568
http://dx.doi.org/10.3762/bjoc.14.59