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Synthesis and characterization of meso-substituted A(2)B corroles with extended π-electronic structure

ABSTRACT: We report the chemical synthesis and characterization of the stable 5,15-bis(pentafluorophenyl)-10-(trimethylsilylethynyl)corrole which serves as a precursor for the subsequent in situ sila-Sonogashira-cross-coupling reaction and metalation with copper(II) acetate. Under ambient conditions...

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Detalles Bibliográficos
Autores principales: Haas, Michael, Gonglach, Sabrina, Müllegger, Stefan, Schöfberger, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5906495/
https://www.ncbi.nlm.nih.gov/pubmed/29681657
http://dx.doi.org/10.1007/s00706-017-2114-6