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Selective electrochemical generation of benzylic radicals enabled by ferrocene-based electron-transfer mediators
The generation and intermolecular functionalisation of carbon-centred radicals has broad potential synthetic utility. Herein, we show that benzylic radicals may be generated electrochemically from benzylboronate derivatives at low electrode potentials (ca. –0.3 V vs. Cp(2)Fe(0/+)) via single electro...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5909123/ https://www.ncbi.nlm.nih.gov/pubmed/29732109 http://dx.doi.org/10.1039/c7sc04032f |