Tracing the ‘9(th) Sulfur’ of the Nitrogenase Cofactor via a Semi-Synthetic Approach

The M-cluster is the [(homocitrate)MoFe(7)S(9)C] active site of nitrogenase that is derived from an 8Fe core assembled via coupling and rearrangement of two [Fe(4)S(4)] clusters concomitant with the insertion of an interstitial carbon and a ‘9(th) sulfur’. Combining synthetic [Fe(4)S(4)] clusters wi...

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Detalles Bibliográficos
Autores principales: Tanifuji, Kazuki, Lee, Chi Chung, Sickerman, Nathaniel S., Tatsumi, Kazuyuki, Ohki, Yasuhiro, Hu, Yilin, Ribbe, Markus W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5910187/
https://www.ncbi.nlm.nih.gov/pubmed/29662207
http://dx.doi.org/10.1038/s41557-018-0029-4

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5910187/
https://www.ncbi.nlm.nih.gov/pubmed/29662207
http://dx.doi.org/10.1038/s41557-018-0029-4

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