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The effect of crystallite size on pressure amplification in switchable porous solids

Negative gas adsorption (NGA) in ordered mesoporous solids is associated with giant contractive structural transitions traversing through metastable states. Here, by systematically downsizing the crystal dimensions of a mesoporous MOF (DUT-49) from several micrometers to less than 200 nm, counterint...

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Detalles Bibliográficos
Autores principales: Krause, Simon, Bon, Volodymyr, Senkovska, Irena, Többens, Daniel M., Wallacher, Dirk, Pillai, Renjith S., Maurin, Guillaume, Kaskel, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5910435/
https://www.ncbi.nlm.nih.gov/pubmed/29679030
http://dx.doi.org/10.1038/s41467-018-03979-2