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The effect of crystallite size on pressure amplification in switchable porous solids
Negative gas adsorption (NGA) in ordered mesoporous solids is associated with giant contractive structural transitions traversing through metastable states. Here, by systematically downsizing the crystal dimensions of a mesoporous MOF (DUT-49) from several micrometers to less than 200 nm, counterint...
Autores principales: | Krause, Simon, Bon, Volodymyr, Senkovska, Irena, Többens, Daniel M., Wallacher, Dirk, Pillai, Renjith S., Maurin, Guillaume, Kaskel, Stefan |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5910435/ https://www.ncbi.nlm.nih.gov/pubmed/29679030 http://dx.doi.org/10.1038/s41467-018-03979-2 |
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