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Polyhedral Cu(2)O to Cu pseudomorphic conversion for stereoselective alkyne semihydrogenation

Cu(2)O cubes, octahedra, and rhombic dodecahedra can be pseudomorphically converted into Cu crystals of corresponding shapes through reduction by ammonia borane in ethanol at 50 °C or below within 3 min, demonstrating the feasibility of making challenging polyhedral metal particles from metal oxide...

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Detalles Bibliográficos
Autores principales: Rej, Sourav, Madasu, Mahesh, Tan, Chih-Shan, Hsia, Chi-Fu, Huang, Michael H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5911822/
https://www.ncbi.nlm.nih.gov/pubmed/29732129
http://dx.doi.org/10.1039/c7sc05232d