Cooperative catalytic methoxycarbonylation of alkenes: uncovering the role of palladium complexes with hemilabile ligands

Mechanistic studies of the catalyst [Pd(2)(dba)(3)/1,1′-bis(tert-butyl(pyridin-2-yl)phosphanyl)ferrocene, L2] for olefin alkoxycarbonylation reactions are described. X-ray crystallography reveals the coordination of the pyridyl nitrogen atom in L2 to the palladium center of the catalytic intermediat...

Descripción completa

Detalles Bibliográficos
Autores principales: Dong, Kaiwu, Sang, Rui, Wei, Zhihong, Liu, Jie, Dühren, Ricarda, Spannenberg, Anke, Jiao, Haijun, Neumann, Helfried, Jackstell, Ralf, Franke, Robert, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5912013/
https://www.ncbi.nlm.nih.gov/pubmed/29732128
http://dx.doi.org/10.1039/c7sc02964k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5912013/
https://www.ncbi.nlm.nih.gov/pubmed/29732128
http://dx.doi.org/10.1039/c7sc02964k

Ejemplares similares