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Cooperative catalytic methoxycarbonylation of alkenes: uncovering the role of palladium complexes with hemilabile ligands

Mechanistic studies of the catalyst [Pd(2)(dba)(3)/1,1′-bis(tert-butyl(pyridin-2-yl)phosphanyl)ferrocene, L2] for olefin alkoxycarbonylation reactions are described. X-ray crystallography reveals the coordination of the pyridyl nitrogen atom in L2 to the palladium center of the catalytic intermediat...

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Detalles Bibliográficos
Autores principales:	Dong, Kaiwu, Sang, Rui, Wei, Zhihong, Liu, Jie, Dühren, Ricarda, Spannenberg, Anke, Jiao, Haijun, Neumann, Helfried, Jackstell, Ralf, Franke, Robert, Beller, Matthias
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5912013/ https://www.ncbi.nlm.nih.gov/pubmed/29732128 http://dx.doi.org/10.1039/c7sc02964k

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