Intramolecular hydrogen-bonding in a cobalt aqua complex and electrochemical water oxidation activity

Water oxidation is catalysed in Nature by a redox cofactor embedded in a hydrogen-bonded network designed to orchestrate proton transfer throughout the challenging 4 electron reaction. In order to mimic aspects of this microenvironment, [CoL(DMA)(CH(3)CN)(2)][BF(4)](2) (2) was synthesized, where L(D...

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Detalles Bibliográficos
Autores principales: Khosrowabadi Kotyk, Juliet F., Hanna, Caitlin M., Combs, Rebecca L., Ziller, Joseph W., Yang, Jenny Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5912104/
https://www.ncbi.nlm.nih.gov/pubmed/29732059
http://dx.doi.org/10.1039/c7sc04960a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5912104/
https://www.ncbi.nlm.nih.gov/pubmed/29732059
http://dx.doi.org/10.1039/c7sc04960a

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