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Intramolecular hydrogen-bonding in a cobalt aqua complex and electrochemical water oxidation activity

Water oxidation is catalysed in Nature by a redox cofactor embedded in a hydrogen-bonded network designed to orchestrate proton transfer throughout the challenging 4 electron reaction. In order to mimic aspects of this microenvironment, [CoL(DMA)(CH(3)CN)(2)][BF(4)](2) (2) was synthesized, where L(D...

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Detalles Bibliográficos
Autores principales:	Khosrowabadi Kotyk, Juliet F., Hanna, Caitlin M., Combs, Rebecca L., Ziller, Joseph W., Yang, Jenny Y.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2018
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5912104/ https://www.ncbi.nlm.nih.gov/pubmed/29732059 http://dx.doi.org/10.1039/c7sc04960a

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