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Heterogeneous Fe(3) single-cluster catalyst for ammonia synthesis via an associative mechanism
The current industrial ammonia synthesis relies on Haber–Bosch process that is initiated by the dissociative mechanism, in which the adsorbed N(2) dissociates directly, and thus is limited by Brønsted–Evans–Polanyi (BEP) relation. Here we propose a new strategy that an anchored Fe(3) cluster on the...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5913218/ https://www.ncbi.nlm.nih.gov/pubmed/29686395 http://dx.doi.org/10.1038/s41467-018-03795-8 |