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Intramolecular hydride transfer onto arynes: redox-neutral and transition metal-free C(sp(3))–H functionalization of amines
Transition metal-free intramolecular hydride transfer onto arynes is reported for the first time. This unique transformation is utilized in redox-neutral intermolecular α-functionalization reactions of different tertiary amines, generating C(sp(3))–C(sp(3)/sp(2)/sp) bonds in a single synthetic opera...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5914459/ https://www.ncbi.nlm.nih.gov/pubmed/29732071 http://dx.doi.org/10.1039/c8sc00181b |