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Catalytic Synthesis of Indolines by Hydrogen Atom Transfer to Cobalt(III)–Carbene Radicals

We report a new method for the synthesis of indolines from o‐aminobenzylidine N‐tosylhydrazones proceeding through a cobalt(III)–carbene radical intermediate. This methodology employs the use of inexpensive commercially available reagents and allows for the transformation of easily derivatized benza...

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Detalles Bibliográficos
Autores principales: Karns, Alexander S., Goswami, Monalisa, de Bruin, Bas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5915749/
https://www.ncbi.nlm.nih.gov/pubmed/29143995
http://dx.doi.org/10.1002/chem.201704626