Copper-catalyzed synthesis of allenylboronic acids. Access to sterically encumbered homopropargylic alcohols and amines by propargylboration

Tri- and tetrasubstituted allenylboronic acids were prepared via a new versatile copper-catalyzed methodology. The densely functionalized allenylboronic acids readily undergo propargylboration reactions with ketones and imines without any additives. Catalytic asymmetric propargylborylation of ketone...

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Detalles Bibliográficos
Autores principales: Zhao, Jian, Jonker, Sybrand J. T., Meyer, Denise N., Schulz, Göran, Tran, C. Duc, Eriksson, Lars, Szabó, Kálmán J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5915797/
https://www.ncbi.nlm.nih.gov/pubmed/29732108
http://dx.doi.org/10.1039/c7sc05123a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5915797/
https://www.ncbi.nlm.nih.gov/pubmed/29732108
http://dx.doi.org/10.1039/c7sc05123a

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