New activation mechanism for half-sandwich organometallic anticancer complexes

The Cp(x) C–H protons in certain organometallic Rh(III) half-sandwich anticancer complexes [(η(5)-Cp(x))Rh(N,N′)Cl](+), where Cp(x) = Cp*, phenyl or biphenyl-Me(4)Cp, and N,N′ = bipyridine, dimethylbipyridine, or phenanthroline, can undergo rapid sequential deuteration of all 15 Cp* methyl protons i...

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Detalles Bibliográficos
Autores principales: Banerjee, Samya, Soldevila-Barreda, Joan J., Wolny, Juliusz A., Wootton, Christopher A., Habtemariam, Abraha, Romero-Canelón, Isolda, Chen, Feng, Clarkson, Guy J., Prokes, Ivan, Song, Lijiang, O'Connor, Peter B., Schünemann, Volker, Sadler, Peter J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5916112/
https://www.ncbi.nlm.nih.gov/pubmed/29732100
http://dx.doi.org/10.1039/c7sc05058e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5916112/
https://www.ncbi.nlm.nih.gov/pubmed/29732100
http://dx.doi.org/10.1039/c7sc05058e

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