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Trend‐Analysis of Solid‐State Structures: Low‐Energy Conformational ‘Reactions’ Involving Directed and Coupled Movements in Half‐Sandwich Compounds [CpFe(CO){C(=O)R}PPh(3)]
Trends in solid‐state structures were used to identify preferred intramolecular movements in half‐sandwich compounds [CpFe(CO){C(=O)R}PPh(3)]. Three weak interactions were analyzed: 1) the CH/π donor–acceptor interaction of phenyl rings in the PPh(3) ligand, 2) the Ph(PPh3) face‐on Cp stabilization,...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5931543/ https://www.ncbi.nlm.nih.gov/pubmed/29744282 http://dx.doi.org/10.1002/open.201800007 |