Cargando…

Redox and photocatalytic properties of a Ni(II) complex with a macrocyclic biquinazoline (Mabiq) ligand

We present a late, first row transition metal photosensitizer that promotes photocatalytic C–C bond formation. The title compound, [Ni(Mabiq)]OTf, as well as its one-electron reduced form, Ni(Mabiq), were synthesized and molecular structures of both were obtained. The electronic structure of the red...

Descripción completa

Detalles Bibliográficos
Autores principales: Grübel, Michael, Bosque, Irene, Altmann, Philipp J., Bach, Thorsten, Hess, Corinna R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5932533/
https://www.ncbi.nlm.nih.gov/pubmed/29780460
http://dx.doi.org/10.1039/c7sc05320g