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Double uranium oxo cations derived from uranyl by borane or silane reduction
A new type of double uranium oxo cation [O–U–O–U–O](4+) is prepared by selective oxygen-atom abstraction from macrocyclic uranyl complexes using either boranes or silanes. A significant degree of multiple U[double bond, length as m-dash]O bonding is evident throughout the U(2)O(3) core, but either t...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5932998/ https://www.ncbi.nlm.nih.gov/pubmed/29589007 http://dx.doi.org/10.1039/c8cc00341f |